A Study of Spectrophotometric Determination of Ion Association Complex, Formed by Anionic Surfactant Sodium Dodecyl by Using Crystal Violet as A Cationic Dye in Region Bilaspur (Chhattisgarh)

Surface active agents (SAA) with negative charge of polar group are named as anionic compounds. They are the main constituent of most products containing synthetic surfactants. Anionic surfactants after use are passed into sewage-treatment plants, where they are partially degraded and adsorbed to sewage sludge. Therefore, it is important to investigate the environmental fate of those classes of compounds in more details. A sensitive, selective and inexpensive method for the determination of anionic surfactants in waste water of sewage has been developed. This research involves determination the concentration of anionic surfactants sodium dodecyl sulphate (SDS) with use appropriated analytical techniques in environmental samples. The official methodology for determination of anionic surfactant (AS) in liquid samples is based on the ion-pair reaction of these analysts’ compounds with crystal violet (CV) and an extraction with organic solvent benzene. In an organic solvent benzene anionic surfactant SDS and a cationic dye CV forms an ion association complex. This ion associate exhibits an absorption maximum wave length (λ max) at 560 nm. The method proposed has been found much easier, accurate and rapid, and there is no use of any toxic chemicals.